Issue 63, 2019

Th@C1(11)-C86: an actinide encapsulated in an unexpected C86 fullerene cage

Abstract

A novel actinide endohedral fullerene with an unexpected chiral cage, Th@C1(11)-C86, was synthesized and characterized. DFT calculations suggest that this low symmetry cage was favoured as a consequence of the strong interaction between Th and the cage, which makes the predictions by the ionic model less reliable for these endohedral mono-metallofullerenes.

Graphical abstract: Th@C1(11)-C86: an actinide encapsulated in an unexpected C86 fullerene cage

Supplementary files

Article information

Article type
Communication
Submitted
17 Jūn. 2019
Accepted
04 Jūl. 2019
First published
04 Jūl. 2019

Chem. Commun., 2019,55, 9271-9274

Th@C1(11)-C86: an actinide encapsulated in an unexpected C86 fullerene cage

Y. Wang, R. Morales-Martínez, W. Cai, J. Zhuang, W. Yang, L. Echegoyen, J. M. Poblet, A. Rodríguez-Fortea and N. Chen, Chem. Commun., 2019, 55, 9271 DOI: 10.1039/C9CC04613E

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