Issue 21, 2018

DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

Abstract

A protocol for the synthesis of allylic sulfides from simple allylic hydrocarbons with thiophenol derivatives via a DDQ-mediated oxidative dehydrogenation strategy is described. This reaction possesses good functional group compatibility, broad substrate scope, and high atom- and step-economy. Moreover, the synthetic utility of this method can be highlighted by its application in the synthesis of versatile organo-sulfur compounds.

Graphical abstract: DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

Supplementary files

Article information

Article type
Research Article
Submitted
31 Jūl. 2018
Accepted
15 Sept. 2018
First published
18 Sept. 2018

Org. Chem. Front., 2018,5, 3158-3162

DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

C. Li, J. Li, C. Tan, W. Wu and H. Jiang, Org. Chem. Front., 2018, 5, 3158 DOI: 10.1039/C8QO00799C

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