Issue 15, 2018

Bis(selenobenzoato)dibutyltin(iv) as a single source precursor for the synthesis of SnSe nanosheets and their photo-electrochemical study for water splitting

Abstract

A new organo-tin complex has been synthesized and used as a single source precursor for the synthesis of SnSe nanosheets by the hot injection method and thin films by the aerosol assisted chemical vapor deposition (AACVD) method. The films were deposited on glass substrates at three different temperatures. The textural quality and preferential growth were found to be significantly altered by changes in the deposition temperature. Oleylamine capped nanosheets and the as-deposited thin films by AACVD were characterized by powder X-ray diffraction (p-XRD) and microscopic techniques. The thin films were also studied by Raman spectroscopy. The stoichiometry is marginally affected by temperature, and all films were slightly selenium deficient. The synthesized material was also evaluated for the photoelectrochemical (PEC) splitting of water. The PEC study revealed the bifunctional nature of the material, which can be applied for both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER), by switching the applied potential.

Graphical abstract: Bis(selenobenzoato)dibutyltin(iv) as a single source precursor for the synthesis of SnSe nanosheets and their photo-electrochemical study for water splitting

Supplementary files

Article information

Article type
Paper
Submitted
22 Janv. 2018
Accepted
13 Marts 2018
First published
14 Marts 2018

Dalton Trans., 2018,47, 5465-5473

Bis(selenobenzoato)dibutyltin(IV) as a single source precursor for the synthesis of SnSe nanosheets and their photo-electrochemical study for water splitting

M. D. Khan, M. Aamir, M. Sohail, M. Sher, N. Baig, J. Akhtar, M. A. Malik and N. Revaprasadu, Dalton Trans., 2018, 47, 5465 DOI: 10.1039/C8DT00285A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements