Issue 21, 2018

Recent advances in molecular rearrangements involving aryne intermediates

Abstract

This Feature Article is aimed at highlighting the recent developments in the transition-metal-free molecular rearrangements involving arynes. The chemistry of arynes has shown incredible developments especially in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions in the last three decades. The rapid growth in this field is mainly due to the development of mild methods for the generation of arynes. One aspect of the recent developments in the chemistry of arynes involves the molecular rearrangements proceeding via this electrophilic intermediate. The molecular rearrangements have provided direct access to a library of valuable molecules, which cannot be accessed in a single step through other synthetic routes. Herein, we present a concise account on the developments that occurred in this field over the last three decades.

Graphical abstract: Recent advances in molecular rearrangements involving aryne intermediates

Article information

Article type
Feature Article
Submitted
27 Nov. 2017
Accepted
30 Janv. 2018
First published
30 Janv. 2018

Chem. Commun., 2018,54, 2580-2594

Recent advances in molecular rearrangements involving aryne intermediates

T. Roy and A. T. Biju, Chem. Commun., 2018, 54, 2580 DOI: 10.1039/C7CC09122B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements