Issue 5, 2017

Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R

Abstract

The selective insertion of a CH2 or NH group at the 5,6-junction on the C59N skeleton is achieved through the PCl5 induced reaction of a CH2OH or NHOH group on the cage to form [C59N(CH2)]R or [C59N(NH)]R, respectively. Spectroscopic data and single crystal X-ray diffraction structure analysis confirmed the 5,6-open homoazafullerene structure.

Graphical abstract: Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R

Supplementary files

Article information

Article type
Research Article
Submitted
06 Febr. 2017
Accepted
15 Febr. 2017
First published
16 Febr. 2017

Org. Chem. Front., 2017,4, 750-754

Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R

D. Xu, Y. Li, N. Lou and L. Gan, Org. Chem. Front., 2017, 4, 750 DOI: 10.1039/C7QO00098G

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