Issue 11, 2017

Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

Abstract

We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of nucleation sites in the primer.

Graphical abstract: Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

Supplementary files

Article information

Article type
Research Article
Submitted
24 Maijs 2017
Accepted
22 Jūn. 2017
First published
30 Jūn. 2017

Mater. Chem. Front., 2017,1, 2256-2260

Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers

M. Rafti, J. A. Allegretto, G. M. Segovia, J. S. Tuninetti, J. M. Giussi, E. Bindini and O. Azzaroni, Mater. Chem. Front., 2017, 1, 2256 DOI: 10.1039/C7QM00235A

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