Issue 17, 2017

Fundamental organometallic chemistry under bimetallic influence: driving β-hydride elimination and diverting migratory insertion at Cu and Ni

Abstract

Bimetallic effects on stoichiometric β-hydride elimination and migratory insertion reactions were examined. Bimetallic reaction conditions drove β-hydride elimination at Cu, while bimetallic C–B elimination occurred in the absence of β-hydrogens. The inherent migratory insertion chemistry of alkynes at Ni was diverted under bimetallic reaction conditions to favor C–H deprotonation.

Graphical abstract: Fundamental organometallic chemistry under bimetallic influence: driving β-hydride elimination and diverting migratory insertion at Cu and Ni

Supplementary files

Article information

Article type
Paper
Submitted
30 Nov. 2016
Accepted
13 Dec. 2016
First published
14 Dec. 2016

Dalton Trans., 2017,46, 5518-5521

Fundamental organometallic chemistry under bimetallic influence: driving β-hydride elimination and diverting migratory insertion at Cu and Ni

T. J. Mazzacano, N. J. Leon, G. W. Waldhart and N. P. Mankad, Dalton Trans., 2017, 46, 5518 DOI: 10.1039/C6DT04533B

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