Issue 100, 2017

An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides

Abstract

We describe the synthesis of an ambiphilic phosphine/H-bond donor ligand featuring a trifluoroacetamide functionality, its coordination to gold(I) chloride, and its application as a self-activating catalyst for the cyclization of propargylamides.

Graphical abstract: An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides

Supplementary files

Article information

Article type
Communication
Submitted
03 Aug. 2017
Accepted
22 Nov. 2017
First published
22 Nov. 2017

Chem. Commun., 2017,53, 13356-13358

An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides

S. Sen and F. P. Gabbaï, Chem. Commun., 2017, 53, 13356 DOI: 10.1039/C7CC06065C

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