Issue 5, 2016
From the journal:

Organic Chemistry Frontiers

Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates†

Kohei Harada,‡a   Marina Nogami,‡a   Keiichi Hirano,*a   Daisuke Kurauchi,a   Hisano Kato,a   Kazunori Miyamoto,a   Tatsuo Saitoa  and  Masanobu Uchiyama*ab  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: k1hirano@mol.f.u-tokyo.ac.jp, uchiyama@mol.f.u-tokyo.ac.jp
Fax: +81 3 5841 0733
Tel: +81 3 5841 0277

b Advanced Elements Chemistry Research Team, RIKEN, RIKEN Center for Sustainable Resource Science, and Elements Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako-shi, Saitama, Japan
E-mail: uchi_yama@riken.jp
Fax: +81 48 467 2869
Tel: +81 48 467 2879

Abstract

A facile and divergent synthetic process for converting tertiary allylic alcohols to multiply substituted allylic boronates is reported. This methodology is especially effective for tertiary alcohol substrates, providing the corresponding allylic boronates in moderate to good yields.

Graphical abstract: Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6QO00009F
Article type
Research Article
Submitted
09 Janv. 2016
Accepted
23 Febr. 2016
First published
01 Marts 2016

Org. Chem. Front., 2016,3, 565-569

Permissions

Request permissions

Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

K. Harada, M. Nogami, K. Hirano, D. Kurauchi, H. Kato, K. Miyamoto, T. Saito and M. Uchiyama, Org. Chem. Front., 2016, 3, 565 DOI: 10.1039/C6QO00009F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements