Issue 19, 2016

Surprising impact of remote groups on the folding–unfolding and dimer-chain equilibria of bifunctional H-bonding unimers

Abstract

Oligoamide 1, consisting of two H-bonding units linked by a trimethylene linker, was previously found to form a very stable, folded dimer. In this work, replacing the side chains and end groups of 1 led to derivatives that show the surprising impact of end groups on the folding and dimer-chain equilibria of the resultant molecules.

Graphical abstract: Surprising impact of remote groups on the folding–unfolding and dimer-chain equilibria of bifunctional H-bonding unimers

  • This article is part of the themed collection: Foldamers

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
09 Janv. 2016
Accepted
28 Janv. 2016
First published
28 Janv. 2016

Chem. Commun., 2016,52, 3773-3776

Surprising impact of remote groups on the folding–unfolding and dimer-chain equilibria of bifunctional H-bonding unimers

R. Liu, S. Cheng, E. S. Baker, R. D. Smith, X. C. Zeng and B. Gong, Chem. Commun., 2016, 52, 3773 DOI: 10.1039/C6CC00224B

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