Issue 4, 2015

Transition-metal-functionalized ordered mesoporous silicas: an overview of sustainable chiral catalysts for enantioselective transformations

Abstract

Transition-metal-catalyzed asymmetric reactions have been demonstrated to be powerful methods for enantioselective construction of various optically pure compounds. The development of ordered mesoporous silica-supported chiral transition-metal-based catalysts and the exploration of their applications represent important progress in green chemistry since such an approach enables an eco-friendly and sustainable catalytic process. In this review, we focus on recent advances in the preparation of ordered mesoporous silica-supported chiral transition-metal-based catalysts and their applications in enantioselective transformations. Firstly, we provide a brief introduction to the modification of ordered mesoporous silicas. We then present in detail, the application of transition-metal-functionalized ordered mesoporous silicas for enantioselective transformations according to various types of reactions. Lastly, prospects for the further development of this research area are discussed.

Graphical abstract: Transition-metal-functionalized ordered mesoporous silicas: an overview of sustainable chiral catalysts for enantioselective transformations

Article information

Article type
Tutorial Review
Submitted
11 Nov. 2014
Accepted
05 Janv. 2015
First published
05 Janv. 2015

Green Chem., 2015,17, 2100-2122

Author version available

Transition-metal-functionalized ordered mesoporous silicas: an overview of sustainable chiral catalysts for enantioselective transformations

T. Cheng, Q. Zhao, D. Zhang and G. Liu, Green Chem., 2015, 17, 2100 DOI: 10.1039/C4GC02204A

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