Issue 4, 2015

Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

Abstract

Organomagnesium reagents enable swift and versatile derivatisation of diarylimines to the corresponding α-substituted diarylmethylamines in excellent yields, through fast and clean reactions. Where it occurs, 1,2-reduction can be circumvented using readily accessible dialkylmagnesium reagents.

Graphical abstract: Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

Supplementary files

Article information

Article type
Communication
Submitted
26 Aug. 2014
Accepted
13 Nov. 2014
First published
13 Nov. 2014

Chem. Commun., 2015,51, 703-706

Author version available

Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

A. Desmarchelier, P. Ortiz and S. R. Harutyunyan, Chem. Commun., 2015, 51, 703 DOI: 10.1039/C4CC06719C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements