Issue 40, 2014

Enhanced oxidative stability of non-Grignard magnesium electrolytes through ligand modification

Abstract

A series of non-Grignard Mg-electrolytes with various para-substituents was synthesized starting from commercially-available phenols. More electron-withdrawing substituents shift the anodic stability of the electrolyte by 400 mV. The p-CF3 substituted phenol exhibits the highest stability of 2.9 V vs. Mg2+/0, and cycles reversibly with the Chevrel-phase Mo6S8 Mg-ion cathode.

Graphical abstract: Enhanced oxidative stability of non-Grignard magnesium electrolytes through ligand modification

Supplementary files

Article information

Article type
Communication
Submitted
23 Sept. 2013
Accepted
25 Nov. 2013
First published
26 Nov. 2013

Chem. Commun., 2014,50, 5193-5195

Enhanced oxidative stability of non-Grignard magnesium electrolytes through ligand modification

E. G. Nelson, J. W. Kampf and B. M. Bartlett, Chem. Commun., 2014, 50, 5193 DOI: 10.1039/C3CC47277A

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