Issue 40, 2014

A two-dimensional hydrogen bonded organic framework self-assembled from a three-fold symmetric carbamate

Abstract

A flexible organic sheet spontaneously assembled under mild conditions from a tri-carbamate. By introducing cyclohexyl side chains as ‘pillars’ between the sheets, a hydrogen bonded organic framework was formed which displayed a capacity for accommodating and releasing guest molecules. The guest size/shape selectivity of the lamellar framework was demonstrated by testing with various guests.

Graphical abstract: A two-dimensional hydrogen bonded organic framework self-assembled from a three-fold symmetric carbamate

Supplementary files

Article information

Article type
Communication
Submitted
18 Sept. 2013
Accepted
01 Nov. 2013
First published
05 Nov. 2013

Chem. Commun., 2014,50, 5209-5211

A two-dimensional hydrogen bonded organic framework self-assembled from a three-fold symmetric carbamate

X. Hou, Z. Wang, M. Overby, A. Ugrinov, C. Oian, R. Singh and Q. R. Chu, Chem. Commun., 2014, 50, 5209 DOI: 10.1039/C3CC47159D

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