Issue 39, 2013

Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

Abstract

A novel mixed-valence Cu(I)–Cu(II) coordination polymer with an infinite two-dimensional structure, [Cu3ICuIIBr3(3,5-Dmpip-dtc)2]n (3,5-Dmpip-dtc = 3,5-dimethylpiperidine dithiocarbamate), was prepared, and its structure was characterized by X-ray diffraction. It shows semiconducting behavior with a relatively small activation energy and high carrier mobility, which were investigated using impedance spectroscopy and flash photolysis time-resolved microwave conductivity measurements, respectively.

Graphical abstract: Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

Supplementary files

Article information

Article type
Communication
Submitted
01 Okt. 2012
Accepted
10 Dec. 2012
First published
19 Dec. 2012

Chem. Commun., 2013,49, 4316-4318

Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

T. Okubo, H. Anma, N. Tanaka, K. Himoto, S. Seki, A. Saeki, M. Maekawa and T. Kuroda-Sowa, Chem. Commun., 2013, 49, 4316 DOI: 10.1039/C2CC37137E

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