Issue 39, 2013

Four-electron reduction of dioxygen catalysed by dinuclear cobalt complexes bridged by bis(terpyridyl)anthracene

Abstract

Dinuclear cobalt-1,10-phenanthroline (1) and 2,2′-bipyridine (2) complexes bridged by 1,8-bis(2,2′:6′,2′′-terpyrid-4′-yl)anthracene (btpyan) were prepared. Both of the complexes selectively catalysed the electrochemical four-electron reduction of dioxygen to H2O without the generation of H2O2 as a two-electron reduction product.

Graphical abstract: Four-electron reduction of dioxygen catalysed by dinuclear cobalt complexes bridged by bis(terpyridyl)anthracene

Supplementary files

Article information

Article type
Communication
Submitted
07 Sept. 2012
Accepted
19 Nov. 2012
First published
20 Nov. 2012

Chem. Commun., 2013,49, 4394-4396

Four-electron reduction of dioxygen catalysed by dinuclear cobalt complexes bridged by bis(terpyridyl)anthracene

T. Wada, H. Maki, T. Imamoto, H. Yuki and Y. Miyazato, Chem. Commun., 2013, 49, 4394 DOI: 10.1039/C2CC36528F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements