Issue 33, 2011

Photocatalytic hydrogen production

Abstract

The efficient storage of solar energy in chemical fuels, such as hydrogen, is essential for the large-scale utilisation of solar energy systems. Recent advances in the photocatalytic production of H2 are highlighted. Two general approaches for the photocatalytic hydrogen generation by homogeneous catalysts are considered: HX (X = Cl, Br) splitting involving both proton reduction and halide oxidationvia an inner-sphere mechanism with a single-component catalyst; and sensitized H2 production, employing sacrificial electron donors to regenerate the active catalyst. Future directions and challenges in photocatalytic H2 generation are enumerated.

Graphical abstract: Photocatalytic hydrogen production

Article information

Article type
Highlight
Submitted
25 Apr. 2011
Accepted
17 Maijs 2011
First published
06 Jūn. 2011

Chem. Commun., 2011,47, 9268-9274

Photocatalytic hydrogen production

T. S. Teets and D. G. Nocera, Chem. Commun., 2011, 47, 9268 DOI: 10.1039/C1CC12390D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements