Issue 20, 2000

Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(i) carbene analogue

Abstract

The reaction between solvent free Li{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6), ‘GaI’ and potassium in toluene afforded Ga{(NDippCMe)2CH} 1 which features a V-shaped, two-coordinate, six-electron gallium(I) center electronically analogous to a singlet carbene carbon.

Supplementary files

Article information

Article type
Communication
Submitted
12 Jūl. 2000
Accepted
06 Sept. 2000
First published
27 Sept. 2000

Chem. Commun., 2000, 1991-1992

Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(I) carbene analogue

N. J. Hardman, B. E. Eichler and P. P. Power, Chem. Commun., 2000, 1991 DOI: 10.1039/B005686N

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