Issue 4, 2024

Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry

Abstract

This review article highlights the diverse ways in which recent developments in the areas of photocatalysis and visible light photochemistry are impacting synthetic carbohydrate chemistry. The major topics covered are photocatalytic glycosylations, generation of radicals at the anomeric position, transformations involving radical formation at non-anomeric positions, additions to glycals, processes initiated by photocatalytic hydrogen atom transfer from sugars, and functional group interconversions at OH and SH groups. Factors influencing stereo- and site-selectivity in these processes, along with mechanistic aspects, are discussed.

Graphical abstract: Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry

Article information

Article type
Review Article
Submitted
12 Okt. 2023
Accepted
13 Dec. 2023
First published
02 Janv. 2024
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2024,15, 1204-1236

Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry

D. J. Gorelik, S. P. Desai, S. Jdanova, J. A. Turner and M. S. Taylor, Chem. Sci., 2024, 15, 1204 DOI: 10.1039/D3SC05400D

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