Issue 4, 2024

Educational series: characterizing crosslinked polymer networks

Abstract

Characterization of polymer networks presents unique challenges due to the insolubility of the materials, but this also enables characterization by new techniques that take advantage of the bulk network structure. An overview of characterization methods for polymer networks is presented, including functionality by IR, swelling and gel fraction calculations, mechanical characterization, thermal characterization, evaluation of molar masses between crosslinks and surface properties. This contribution serves as a reference for researchers aiming to evaluate network properties for the first time, or to expand the range of techniques used in network characterization.

Graphical abstract: Educational series: characterizing crosslinked polymer networks

Article information

Article type
Tutorial Review
Submitted
06 Aug. 2023
Accepted
18 Dec. 2023
First published
19 Dec. 2023
This article is Open Access
Creative Commons BY-NC license

Polym. Chem., 2024,15, 219-247

Educational series: characterizing crosslinked polymer networks

C. W. H. Rajawasam, O. J. Dodo, M. A. S. N. Weerasinghe, I. O. Raji, S. V. Wanasinghe, D. Konkolewicz and N. De Alwis Watuthanthrige, Polym. Chem., 2024, 15, 219 DOI: 10.1039/D3PY00914A

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