Issue 8, 2024

Metal–organic frameworks for petroleum-based platform compound separations

Abstract

The advancement of separation technology is not only conducive to lowering energy consumption, but also opens an avenue to obtain the world's key resources. Metal–organic frameworks (MOFs), a novel type of porous materials, have unique advantages in separation and purification compared with traditional adsorbents and separation technologies, especially in the separation of petroleum-based platform compounds, owing to their advantages of easy structure regulation and functionalization. Significant advancements have been achieved in the separation of binary component petroleum-based platform compounds based on MOFs. However, industrial gas mixtures often exist in multiple components. In contrast to the rapid development of binary mixture separations, the separation of ternary and even multi-component mixtures is much more difficult and rarely achieved with a single material. This review briefly introduces the adsorptive separation technology and its mechanism based on MOFs. Next, recent advances in MOFs for the separation of multiple-component petroleum-based platform compounds (C2H2/C2H4/C2H6/CO2, C3H4/C3H6/C3H8, butane/butene/isobutene/1,3-butadiene, trans-2-pentene/1-pentene/isoprene, n-hexane/2-methylpentane/3-methylpentane/2,2-dimethylbutane/2,3-dimethylbutane, o-xylene/m-xylene/p-xylene/ethylbenzene, etc.) are presented to guide more complex chemical separation processes. Furthermore, inherent obstacles and future development prospects from academia to eventual industrial implementation are presented. Based on adsorptive separation technology, we are committed to exploring an alternative separation route that is energy-efficient and environmentally friendly and strives to achieve the high-efficiency separation of multi-component petroleum-based platform compounds.

Graphical abstract: Metal–organic frameworks for petroleum-based platform compound separations

Article information

Article type
Review Article
Submitted
06 Dec. 2023
Accepted
08 Marts 2024
First published
10 Marts 2024
This article is Open Access
Creative Commons BY-NC license

Mater. Adv., 2024,5, 3135-3157

Metal–organic frameworks for petroleum-based platform compound separations

X. Zhang, X. Wang, F. Gao, Y. Chen, H. Liu, P. Zhou, Z. Kang, Y. Wang and W. Fan, Mater. Adv., 2024, 5, 3135 DOI: 10.1039/D3MA01085F

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements