Issue 15, 2024

Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N2)2(diphosphine)2 complexes

Abstract

The synthesis, characterization of trans-[Cr(N2)2(depe)2] (1) is described. 1 and trans-[Cr(N2)2(dmpe)2] (2) catalyze the reduction of N2 to N2H4 and NH3 in THF using SmI2 and H2O or ethylene glycol as proton sources. 2 produces the highest total fixed N for a molecular Cr catalyst to date.

Graphical abstract: Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N2)2(diphosphine)2 complexes

Supplementary files

Article information

Article type
Communication
Submitted
08 Marts 2024
Accepted
25 Marts 2024
First published
26 Marts 2024

Dalton Trans., 2024,53, 6496-6500

Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N2)2(diphosphine)2 complexes

C. H. Beasley, O. L. Duletski, K. S. Stankevich, N. Arulsamy and M. T. Mock, Dalton Trans., 2024, 53, 6496 DOI: 10.1039/D4DT00702F

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