Issue 11, 2024

Reactivity of metal dioxo complexes

Abstract

Metal dioxo chemistry and its diverse reactivity are presented with an emphasis on the mechanisms of reactivity. Work from approximately the last decade is surveyed and organized by metal. In particular, the chemistry of cis-dioxo metal complexes is discussed at length. Reactions are grouped by generic type, including addition across a metal oxo bond, oxygen atom transfer, and radical atom transfer reactions. Attention is given to advances in deoxygenation chemistry, oxidation chemistry, and reductive transformations.

Graphical abstract: Reactivity of metal dioxo complexes

Article information

Article type
Perspective
Submitted
31 Dec. 2023
Accepted
07 Febr. 2024
First published
21 Febr. 2024

Dalton Trans., 2024,53, 4874-4889

Reactivity of metal dioxo complexes

C. A. Canote and S. M. Kilyanek, Dalton Trans., 2024, 53, 4874 DOI: 10.1039/D3DT04390H

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