Tetraphenylpentalenide organolanthanide complexes

Nicholas J. Katzer; Mandeep Kaur; Asmita Sen; Rupal Nimaiyar; Jochen Autschbach; Polly L. Arnold; Ulrich Hintermair

doi:10.1039/D4CC02570A

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Tetraphenylpentalenide organolanthanide complexes†

Nicholas J. Katzer,

‡^ab Mandeep Kaur,

‡^c Asmita Sen,

‡^d Rupal Nimaiyar,^a Jochen Autschbach,

*^d Polly L. Arnold

*^ab and Ulrich Hintermair

*^c

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of California, Berkeley, CA, USA
E-mail: pla@berkeley.edu

^b Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

^c Department of Chemistry, University of Bath, UK
E-mail: u.hintermair@bath.ac.uk

^d Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA
E-mail: jochena@buffalo.edu

Abstract

The D_2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) Ln^III sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.

This article is part of the themed collections: Chemical Communications HOT Articles 2024 and 2024 Pioneering Investigators

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DOI: https://doi.org/10.1039/D4CC02570A
Article type: Communication
Submitted: 27 Maijs 2024
Accepted: 08 Jūl. 2024
First published: 12 Jūl. 2024
This article is Open Access

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Chem. Commun., 2024,60, 9749-9752

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Tetraphenylpentalenide organolanthanide complexes

N. J. Katzer, M. Kaur, A. Sen, R. Nimaiyar, J. Autschbach, P. L. Arnold and U. Hintermair, Chem. Commun., 2024, 60, 9749 DOI: 10.1039/D4CC02570A

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Chemical Communications

Tetraphenylpentalenide organolanthanide complexes†

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Tetraphenylpentalenide organolanthanide complexes

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