Issue 10, 2024

Tailoring the subshell and electronic structure of an atomically precise AuAg alloy nanocluster

Abstract

Manipulating the atomic-level structure of the subshell of a nanocluster while preserving the inner and outer shell structure is challenging. We present the synthesis and molecular structure of an alkynyl-protected Au34Ag27 nanocluster, which exhibits distinct third shell atomic arrangement, electronic structure, and optical properties from those of the Au34Ag28 nanocluster.

Graphical abstract: Tailoring the subshell and electronic structure of an atomically precise AuAg alloy nanocluster

Supplementary files

Article information

Article type
Communication
Submitted
07 Sept. 2023
Accepted
20 Dec. 2023
First published
29 Dec. 2023

Chem. Commun., 2024,60, 1289-1292

Tailoring the subshell and electronic structure of an atomically precise AuAg alloy nanocluster

G. Deng, T. Ki, X. Liu, Y. Chen, K. Lee, S. Yoo, Q. Tang, M. S. Bootharaju and T. Hyeon, Chem. Commun., 2024, 60, 1289 DOI: 10.1039/D3CC04432G

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