Issue 25, 2023

Dual metal site-mediated efficient C–N coupling toward electrochemical urea synthesis

Abstract

Electrochemical urea synthesis is a promising technology for carbon utilization. Herein, we report a CoPc–MoS2 system for promoting urea synthesis by a C–N coupling reaction. Dual metal sites mediate N2 activation and CO2 adsorption insertion to produce a urea yield of 175.6 μg h−1 mgcat−1 at −0.7 V vs. RHE.

Graphical abstract: Dual metal site-mediated efficient C–N coupling toward electrochemical urea synthesis

Supplementary files

Article information

Article type
Communication
Submitted
17 Febr. 2023
Accepted
15 Maijs 2023
First published
17 Maijs 2023

J. Mater. Chem. A, 2023,11, 13249-13254

Dual metal site-mediated efficient C–N coupling toward electrochemical urea synthesis

S. Paul, S. Sarkar, A. Adalder, A. Banerjee and U. K. Ghorai, J. Mater. Chem. A, 2023, 11, 13249 DOI: 10.1039/D3TA01011B

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