Issue 79, 2023

Binding modes of high stoichiometry guest complexes with a Co8L12 cage uncovered by mass spectrometry

Abstract

We demonstrate how different modes of guest binding with a Co8L12 cubic cage can be determined using ESI-MS. High stoichiometry guest binding was observed, with the guests preferentially binding externally, but internal guest inclusion was also seen at higher guest loading.

Graphical abstract: Binding modes of high stoichiometry guest complexes with a Co8L12 cage uncovered by mass spectrometry

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug. 2023
Accepted
12 Sept. 2023
First published
13 Sept. 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 11811-11814

Binding modes of high stoichiometry guest complexes with a Co8L12 cage uncovered by mass spectrometry

D. L. Stares, C. Mozaceanu, M. D. Ward and C. A. Schalley, Chem. Commun., 2023, 59, 11811 DOI: 10.1039/D3CC04291J

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