Issue 94, 2023

Probing the magnetic and magneto-optical properties of a radical-bridged Tb4 single-molecule magnet

Abstract

Reaction of the 1,2,4,5-tetrazine (tz˙) radical and {Cp*2Tb}+ has yielded a tetranuclear radical-bridged TbIII single-molecule magnet. The strong Ln–radical coupling and the electronic differences of the TbIII ions in [(Cp*2Tb)4(tz˙)4]·3C6H6 (1) are probed via magnetic, magneto-optical and computational studies.

Graphical abstract: Probing the magnetic and magneto-optical properties of a radical-bridged Tb4 single-molecule magnet

Supplementary files

Article information

Article type
Communication
Submitted
23 Jūn. 2023
Accepted
29 Okt. 2023
First published
30 Okt. 2023

Chem. Commun., 2023,59, 13970-13973

Probing the magnetic and magneto-optical properties of a radical-bridged Tb4 single-molecule magnet

N. Mavragani, A. A. Kitos, D. A. Gálico, A. Mansikkamäki and M. Murugesu, Chem. Commun., 2023, 59, 13970 DOI: 10.1039/D3CC03034B

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