Issue 62, 2023

C–C bond formation via photocatalytic direct functionalization of simple alkanes

Abstract

The direct functionalization of alkanes represents a very important challenge in the goal to develop more atom-efficient and clean C–C bond forming reactions. These processes, however, are hampered by the low reactivity of the aliphatic C–H bonds. Photocatalytic processes based on hydrogen atom transfer C–H bond activation strategies have become a useful tool to activate and functionalize these inert compounds. In this article, we summarize the main achievements in this field applied to the development of C–C bond forming reactions, and we discuss the key mechanistic features that enable these transformations.

Graphical abstract: C–C bond formation via photocatalytic direct functionalization of simple alkanes

Article information

Article type
Highlight
Submitted
09 Jūn. 2023
Accepted
28 Jūn. 2023
First published
29 Jūn. 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 9424-9444

C–C bond formation via photocatalytic direct functionalization of simple alkanes

Á. Velasco-Rubio, P. Martínez-Balart, A. M. Álvarez-Constantino and M. Fañanás-Mastral, Chem. Commun., 2023, 59, 9424 DOI: 10.1039/D3CC02790B

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements