Issue 41, 2023

NDIPhos as a platform for chiral supramolecular ligands in rhodium-catalyzed enantioselective hydrogenation

Abstract

Chiral naphthalene diimide ligands (NDIPhos) were exploited in rhodium-catalyzed enantioselective hydrogenation. The key feature of these ligands is their ability to self-assemble via π–π interactions to mimic bidentate ligands, offering a complementary method to traditional supramolecular strategies. This concept was further substantiated by computations with the composite electronic-structure method r2SCAN-3c.

Graphical abstract: NDIPhos as a platform for chiral supramolecular ligands in rhodium-catalyzed enantioselective hydrogenation

Supplementary files

Article information

Article type
Communication
Submitted
14 Febr. 2023
Accepted
25 Apr. 2023
First published
26 Apr. 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 6231-6234

NDIPhos as a platform for chiral supramolecular ligands in rhodium-catalyzed enantioselective hydrogenation

G. Force, R. J. Mayer, M. Vayer and D. Lebœuf, Chem. Commun., 2023, 59, 6231 DOI: 10.1039/D3CC00695F

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