Issue 7, 2022

Single crystal field-effect transistor of tetrabenzoporphyrin with a one-dimensionally extended columnar packing motif exhibiting efficient charge transport properties

Abstract

5,15-Bis(triisopropylsilyl)ethynyltetrabenzoporphyrin (TIPS-H2BP) gave a one-dimensionally extended columnar packing motif. The single crystal field-effect transistor of TIPS-H2BP exhibited clearly better hole mobility (2.16 cm2 V−1 s−1) than its metal complexes (ca. 0.1 cm2 V−1 s−1), with efficient charge transport through π–π stacking along the tetrabenzoporphyrin units.

Graphical abstract: Single crystal field-effect transistor of tetrabenzoporphyrin with a one-dimensionally extended columnar packing motif exhibiting efficient charge transport properties

Supplementary files

Article information

Article type
Communication
Submitted
30 Jūl. 2021
Accepted
08 Sept. 2021
First published
09 Sept. 2021

J. Mater. Chem. C, 2022,10, 2527-2531

Author version available

Single crystal field-effect transistor of tetrabenzoporphyrin with a one-dimensionally extended columnar packing motif exhibiting efficient charge transport properties

J. Zhu, H. Hayashi, M. Chen, C. Xiao, K. Matsuo, N. Aratani, L. Zhang and H. Yamada, J. Mater. Chem. C, 2022, 10, 2527 DOI: 10.1039/D1TC03547A

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