Issue 11, 2022

Hybrid palladium nanoparticles and nickel single atom catalysts for efficient electrocatalytic ethanol oxidation

Abstract

The electrocatalytic ethanol oxidation reaction (EOR) is a critical component of direct ethanol fuel cells, while its reactivity, stability, and selectivity toward C1 products are severely hindered by the poisoning effect of CO species on the surface of noble-metal catalysts. In this work, we developed a hybrid material of palladium nanoparticles and nickel single-atom catalysts (Pd NPs@Ni SAC) for efficient EOR. The Pd nanoparticles catalyze the breaking of carbon–carbon bonds of ethanol, while the adsorbed CO intermediates are removed by the Ni single-atom catalyst. The Pd NPs@Ni SAC structure exhibits outstanding EOR performances, including high mass activity, good selectivities of C1 products, and excellent electrocatalytic stability. Our work suggests an attractive perspective of utilizing single-atom electrocatalysts for ethanol oxidation.

Graphical abstract: Hybrid palladium nanoparticles and nickel single atom catalysts for efficient electrocatalytic ethanol oxidation

Supplementary files

Article information

Article type
Paper
Submitted
01 Okt. 2021
Accepted
15 Nov. 2021
First published
15 Nov. 2021

J. Mater. Chem. A, 2022,10, 6129-6133

Hybrid palladium nanoparticles and nickel single atom catalysts for efficient electrocatalytic ethanol oxidation

S. Li, A. Guan, H. Wang, Y. Yan, H. Huang, C. Jing, L. Zhang, L. Zhang and G. Zheng, J. Mater. Chem. A, 2022, 10, 6129 DOI: 10.1039/D1TA08518B

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