Issue 5, 2022

Achieving performance and longevity with butane-operated low-temperature solid oxide fuel cells using low-cost Cu and CeO2 catalysts

Abstract

The use of thin-film solid oxide fuel cells (TF-SOFCs) can effectively lower the operating temperature of a typical solid oxide fuel cell (SOFC) below 600 °C, while maintaining high efficiency and using low-cost catalysts. However, the fuel flexibility in SOFCs becomes a significant challenge at lower operating temperatures, resulting in the need for expensive noble-metal catalysts. The effective implementation of low-cost catalysts, Cu and CeO2, in a TF-SOFC presents a solution to this problem. Cu is inserted directly near the electrolyte–anode interface via a combination of pulsed laser deposition and sputtering to assist the electrochemical reactions, and the anode support, which constitutes the main volume of the cell, is infiltrated with CeO2 to effectively facilitate thermochemical reforming reactions. A comprehensive study of catalyst-modified cells (Cu–Ce-cell, Ce-cell, and Cu-cell) and a Ni/YSZ reference cell (ref-cell) is performed over n-butane fuel in an operating temperature range of 500 to 600 °C. The cell incorporating Cu and CeO2 (Cu–Ce-cell) shows a record high performance for a hydrocarbon-fueled SOFC, with a peak power density of 1120 mW cm−2 at 600 °C. Cu and CeO2 improve the activity of the steam reforming reaction, and CeO2 expands the triple-phase boundary, increasing the electrochemical activity. Cu–Ce-cell also degrades at a much slower rate than ref-cell. Post-reaction analysis proves that the drastic improvement in longevity is achieved as a result of the enhanced carbon deposition resistance of Cu–Ce-cell.

Graphical abstract: Achieving performance and longevity with butane-operated low-temperature solid oxide fuel cells using low-cost Cu and CeO2 catalysts

Supplementary files

Article information

Article type
Paper
Submitted
13 Aug. 2021
Accepted
24 Okt. 2021
First published
26 Okt. 2021

J. Mater. Chem. A, 2022,10, 2460-2473

Achieving performance and longevity with butane-operated low-temperature solid oxide fuel cells using low-cost Cu and CeO2 catalysts

C. Thieu, S. Yang, H. Ji, H. Kim, K. J. Yoon, J. Lee and J. Son, J. Mater. Chem. A, 2022, 10, 2460 DOI: 10.1039/D1TA06922E

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