Issue 12, 2022

Narrowband blue emission with insensitivity to the doping concentration from an oxygen-bridged triarylboron-based TADF emitter: nondoped OLEDs with a high external quantum efficiency up to 21.4%

Abstract

Blue thermally activated delayed fluorescence (TADF) emitters that can simultaneously achieve narrowband emission and high efficiency in nondoped organic light-emitting diodes (OLEDs) remain a big challenge. Herein, we successfully design and synthesize two blue TADF emitters by directly incorporating carbazole fragments into an oxygen-bridged triarylboron acceptor. Depending on the linking mode, the two emitters show significantly different photophysical properties. Benefitting from the bulky steric hindrance between the acceptor and terminal pendants, the blue emitter TDBA-Cz exhibited a high photoluminescence quantum yield (PLQY) of 88% in neat films and narrowband emission. The corresponding non-doped blue device exhibited a maximum external quantum efficiency (EQE) of 21.4%, with a full width at half maximum (FWHM) of only 45 nm. This compound is the first blue TADF emitter that can concurrently achieve narrow bandwidth and high electroluminescence (EL) efficiency in nondoped blue TADF-OLEDs.

Graphical abstract: Narrowband blue emission with insensitivity to the doping concentration from an oxygen-bridged triarylboron-based TADF emitter: nondoped OLEDs with a high external quantum efficiency up to 21.4%

Supplementary files

Article information

Article type
Edge Article
Submitted
18 Janv. 2022
Accepted
21 Febr. 2022
First published
21 Febr. 2022
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2022,13, 3402-3408

Narrowband blue emission with insensitivity to the doping concentration from an oxygen-bridged triarylboron-based TADF emitter: nondoped OLEDs with a high external quantum efficiency up to 21.4%

J. Han, Z. Huang, J. Miao, Y. Qiu, Z. Xie and C. Yang, Chem. Sci., 2022, 13, 3402 DOI: 10.1039/D2SC00329E

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