Issue 10, 2022

Two-dimensional heterostructures built from ultrathin CeO2 nanosheet surface-coordinated and confined metal–organic frameworks with enhanced stability and catalytic performance

Abstract

Two-dimensional (2D) metal–organic framework (MOF) based heterostructures will be greatly advantageous to enhance catalytic performance because they increase the contact surface and charge transfer. Herein, a novel 2D heterostructure named CeO2@NiFe-MOFs, in which monolayer NiFe-MOFs is coordinated with ceria (CeO2) to improve catalytic and stability performance, is successfully constructed by the strategy of in situ growth on the surface of ultrathin CeO2 nanosheets being functionalized with monolayer carboxylic acid groups. The 2D heterostructure possesses a sandwich structure, where monolayer NiFe-MOFs are coordinated to both the top and bottom surface of CeO2 nanosheets via joining carboxylic acid groups. In particular, CeO2 with robust coordination plays a significant role in the anchoring of carboxylic acid groups and binding strength of heterostructures. The 2D CeO2@NiFe-MOF heterostructure with a joint effect of metal–ligand coordination not only presents good structural stability but also significantly enhances the oxygen evolution reaction (OER) efficiencies in comparison to bare NiFe-MOFs, achieving a current density of 20 mA cm−2 at a low overpotential of 248 mV as well as durability for at least 40 h. Meanwhile, the electronics, optics, band gap energy and local strains of CeO2 decorated with 2D NiFe-MOFs are different to the properties of bare CeO2. Our study on the construction of an ultrathin CeO2 surface-coordinated and confined MOF layer may pave a new way for novel 2D MOF composites/heterostructures or multi-functional 2D CeO2 materials to be used in energy conversion or other fields.

Graphical abstract: Two-dimensional heterostructures built from ultrathin CeO2 nanosheet surface-coordinated and confined metal–organic frameworks with enhanced stability and catalytic performance

Supplementary files

Article information

Article type
Edge Article
Submitted
18 Janv. 2022
Accepted
12 Febr. 2022
First published
14 Febr. 2022
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2022,13, 3035-3044

Two-dimensional heterostructures built from ultrathin CeO2 nanosheet surface-coordinated and confined metal–organic frameworks with enhanced stability and catalytic performance

H. An, Y. Hu, N. Song, T. Mu, S. Bai, Y. Peng, L. Liu and Y. Tang, Chem. Sci., 2022, 13, 3035 DOI: 10.1039/D2SC00308B

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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