Issue 19, 2022

Status and gaps toward fossil-free sustainable chemical production

Abstract

Chemical production needs to transform radically toward fossil-free sustainable chemical production to meet the targets for net-zero emissions by the year 2050. The feasibility of this transformation, the motivations, status and gaps, and perspectives are discussed after introducing how this change also implies a change in the model of production. Realizing the defossilization of chemical production involves electrifying the chemical processes, especially crucial elements such as chemical reactors, and the direct use of renewable energy to drive the chemical reaction. With a focus on electrocatalysis, the most relevant cases of (i) light olefin production, (ii) direct synthesis of main intermediates such as formaldehyde and acetic acid, and (iii) the production of aromatics are analyzed. The feasibility of these routes in the short–medium term is shown, while other cases such as the direct synthesis of ammonia from N2 require turning the approach to other directions. On a global scale, defossilization of chemical production is feasible in the medium–long term with a cut of over 800 Mt per year CO2 eq. emissions in line with the expectation to reach the net-zero emission target. A final section introduces a short discussion about some critical questions regarding the sustainability of fossil-free chemical production.

Graphical abstract: Status and gaps toward fossil-free sustainable chemical production

Article information

Article type
Perspective
Submitted
26 Apr. 2022
Accepted
23 Aug. 2022
First published
24 Aug. 2022
This article is Open Access
Creative Commons BY-NC license

Green Chem., 2022,24, 7305-7331

Status and gaps toward fossil-free sustainable chemical production

G. Centi and S. Perathoner, Green Chem., 2022, 24, 7305 DOI: 10.1039/D2GC01572B

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