Issue 12, 2022

Photoinduced cascade cyclization of alkynes with NH4SCN: access to SCN-containing dibenzazepines or dioxodibenzothiazepines

Abstract

Photoinduced radical cascade cyclization of aryl acetylenes with NH4SCN was achieved, which provides a simple and mild protocol for the synthesis of SCN-containing dibenzazepines or dioxodibenzothiazepines. A variety of scaled-up operations, functional group transformations, radical capture studies and on/off light experiments were performed to test the merits of the desired products and the reaction process.

Graphical abstract: Photoinduced cascade cyclization of alkynes with NH4SCN: access to SCN-containing dibenzazepines or dioxodibenzothiazepines

Supplementary files

Article information

Article type
Communication
Submitted
02 Apr. 2022
Accepted
17 Maijs 2022
First published
19 Maijs 2022

Green Chem., 2022,24, 4742-4747

Photoinduced cascade cyclization of alkynes with NH4SCN: access to SCN-containing dibenzazepines or dioxodibenzothiazepines

S. Chen, Q. Yan, J. Fan, Y. Gao, X. Yang, L. Li, Z. Liu and Z. Li, Green Chem., 2022, 24, 4742 DOI: 10.1039/D2GC01276F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements