Issue 86, 2022

Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

Abstract

The solution-state structure of an amine-functionalised Cu24L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.

Graphical abstract: Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

Supplementary files

Article information

Article type
Communication
Submitted
08 Sept. 2022
Accepted
05 Okt. 2022
First published
06 Okt. 2022

Chem. Commun., 2022,58, 12122-12125

Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption

M. L. Schneider, J. A. Campbell, A. D. Slattery and W. M. Bloch, Chem. Commun., 2022, 58, 12122 DOI: 10.1039/D2CC04969D

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