Issue 63, 2022

Zr4+-terephthalate MOFs with 6-connected structures, highly efficient As(iii/v) sorption and superhydrophobic properties

Abstract

The use of terephthalate ligands with CnH2n+1NH-chains (n ≥ 6) led to the isolation of the first examples of Zr4+-terephthalate MOFs with 6-connected frameworks. The material with hexyl-amino functional groups has been proved to be an exceptional sorbent for the removal of As(III/V) toxic species from aqueous media, whereas MOFs with heptyl to dodecyl-amino moieties are superhydrophobic with promising oil–water separation properties.

Graphical abstract: Zr4+-terephthalate MOFs with 6-connected structures, highly efficient As(iii/v) sorption and superhydrophobic properties

Supplementary files

Article information

Article type
Communication
Submitted
31 Maijs 2022
Accepted
14 Jūl. 2022
First published
14 Jūl. 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 8862-8865

Zr4+-terephthalate MOFs with 6-connected structures, highly efficient As(III/V) sorption and superhydrophobic properties

A. D. Pournara, S. Rizogianni, D. A. Evangelou, E. K. Andreou, G. S. Armatas and M. J. Manos, Chem. Commun., 2022, 58, 8862 DOI: 10.1039/D2CC03090J

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