Issue 59, 2022

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

Abstract

The synthesis of particular cyclopropane-tethered 1,5-enynes, namely 6-alkynyl-4-alkylidenebicyclo[3.1.0]hex-2-enes, enabled the discovery of unprecedented gold-catalyzed rearrangment to indenes. A computational study of the mechanism of this profound skeleton rearrangement is also disclosed.

Graphical abstract: Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

Supplementary files

Article information

Article type
Communication
Submitted
20 Maijs 2022
Accepted
22 Jūn. 2022
First published
22 Jūn. 2022

Chem. Commun., 2022,58, 8206-8209

Gold-catalysed rearrangement of unconventional cyclopropane-tethered 1,5-enynes

R. Vicente, E. Tudela, M. A. Rodríguez, Á. L. Suárez-Sobrino and A. Ballesteros, Chem. Commun., 2022, 58, 8206 DOI: 10.1039/D2CC02869G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements