Issue 16, 2022

Utilization of BODIPY-based redox events to manipulate the Lewis acidity of fluorescent boranes

Abstract

This report describes the implementation of a 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dye into the ligand framework of a borane. The redox-active nature of the BODIPY dye is utilized to generate a family of molecular boranes that are capable of exhibiting tunable Lewis acidities through BODIPY-based redox events.

Graphical abstract: Utilization of BODIPY-based redox events to manipulate the Lewis acidity of fluorescent boranes

Supplementary files

Article information

Article type
Communication
Submitted
12 Nov. 2021
Accepted
21 Dec. 2021
First published
04 Janv. 2022

Chem. Commun., 2022,58, 2646-2649

Author version available

Utilization of BODIPY-based redox events to manipulate the Lewis acidity of fluorescent boranes

B. L. Thompson, I. A. Kieffer and Z. M. Heiden, Chem. Commun., 2022, 58, 2646 DOI: 10.1039/D1CC06400B

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