Issue 2, 2022

Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis

Abstract

Metallaphoto-catalysis has been established as a robust platform for efficient construction of a range of chemical bonds. Moreover, transformation of native functionalities such as C(sp3)–H bonds to produce functional molecules represents one of the most attractive strategies in organic synthesis. Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp3)–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.

Graphical abstract: Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis

Article information

Article type
Feature Article
Submitted
07 Nov. 2021
Accepted
06 Dec. 2021
First published
06 Dec. 2021
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 171-184

Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis

H. Yue, C. Zhu, L. Huang, A. Dewanji and M. Rueping, Chem. Commun., 2022, 58, 171 DOI: 10.1039/D1CC06285A

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