Issue 39, 2021

Revealing the internal heavy chalcogen atom effect on the photophysics of the dibenzo[a,j]phenazine-cored donor–acceptor–donor triad

Abstract

A new twisted donor–acceptor–donor (D–A–D) multi-photofunctional organic molecule comprising phenoselenazine as the electron donor (Ds) and dibenzo[a,j]phenazine (DBPHZ) as the electron acceptor (A) has been developed. The developed selenium-incorporated D–A–D compound features multi-color polymorphism, distinct mechanochromic luminescence, chemically-stimulated luminochromism, thermally-activated delayed fluorescence, and room-temperature phosphorescence. The internal heavy atom effect on the photophysical properties of the D–A–D system has been investigated through a comparison with the physicochemical properties of a previously developed sulfur analogue and a tellurium analogue.

Graphical abstract: Revealing the internal heavy chalcogen atom effect on the photophysics of the dibenzo[a,j]phenazine-cored donor–acceptor–donor triad

Supplementary files

Article information

Article type
Paper
Submitted
08 Jūn. 2021
Accepted
20 Aug. 2021
First published
24 Aug. 2021

J. Mater. Chem. C, 2021,9, 13942-13953

Revealing the internal heavy chalcogen atom effect on the photophysics of the dibenzo[a,j]phenazine-cored donor–acceptor–donor triad

S. Goto, Y. Nitta, N. O. Decarli, L. E. de Sousa, P. Stachelek, N. Tohnai, S. Minakata, P. de Silva, P. Data and Y. Takeda, J. Mater. Chem. C, 2021, 9, 13942 DOI: 10.1039/D1TC02635F

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