Issue 41, 2021

Selective hydroxylation of aryl iodides to produce phenols under mild conditions using a supported copper catalyst

Abstract

Owing to the high activity and low-cost, copper-based catalysts are promising candidates for transforming aromatic halides to yield phenols. In this work, we report the selective hydroxylation of aromatic iodides to produce phenols using an atomically dispersed copper catalyst (Cu–ZnO–ZrO2) under mild reaction conditions. The reactions were conducted without the use of additional organic ligands, and the protection of an inert atmosphere environment is not required. The catalyst can be easily prepared, scalable, and is very efficient for a wide range of substrates. The catalytic reactions can be carried out with only 1.24 mol% Cu loading, which shows great potential in mass production.

Graphical abstract: Selective hydroxylation of aryl iodides to produce phenols under mild conditions using a supported copper catalyst

Supplementary files

Article information

Article type
Paper
Submitted
26 Maijs 2021
Accepted
14 Jūl. 2021
First published
21 Jūl. 2021
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2021,11, 25348-25353

Selective hydroxylation of aryl iodides to produce phenols under mild conditions using a supported copper catalyst

L. Hao, A. Auni, G. Ding, X. Li, H. Xu, T. Li and Q. Zhang, RSC Adv., 2021, 11, 25348 DOI: 10.1039/D1RA04112F

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