Issue 2, 2021

Ba2B7O12F with novel FBB [B7O16F] and deep-ultraviolet cut-off edge

Abstract

A new member in the barium fluorooxoborate family, namely Ba2B7O12F, was obtained by the high-temperature solution method in an open system under ambient pressure. The structure features a new fundamental building block [B7O16F], which interconnects with each other to form the anionic framework [B7O12F] with two different caves in which the cations reside. The experiment result indicates that Ba2B7O12F possesses a deep-ultraviolet cut-off edge below 180 nm.

Graphical abstract: Ba2B7O12F with novel FBB [B7O16F] and deep-ultraviolet cut-off edge

Supplementary files

Article information

Article type
Research Article
Submitted
03 Aug. 2020
Accepted
29 Okt. 2020
First published
30 Okt. 2020

Inorg. Chem. Front., 2021,8, 339-343

Ba2B7O12F with novel FBB [B7O16F] and deep-ultraviolet cut-off edge

Z. Miao, Y. Yang, Z. Wei, Z. Yang and S. Pan, Inorg. Chem. Front., 2021, 8, 339 DOI: 10.1039/D0QI00924E

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