Issue 45, 2021

Precursor chemistry of metal nitride nanocrystals

Abstract

Metal nitride nanocrystals are a versatile class of nanomaterials. Depending on their chemical composition, the optical properties vary from those of traditional semiconductor nanocrystals (called quantum dots) to more metallic character (featuring a plasmon resonance). However, the synthesis of colloidal metal nitride nanocrystals is challenging since the underlying precursor chemistry is much less developed compared to the chemistry of metal, metal chalcogenide or metal phosphide nanocrystals. Here, we review chemical approaches that lead (or could lead) to the formation of colloidally stable metal nitride nanocrystals. By systematically comparing different synthetic approaches, we uncover trends and gain insight into the chemistry of these challenging materials. We also discuss and critically evaluate the plausibility of certain suggested mechanisms. This review is meant as a guide for the further development of colloidal nitride nanocrystals.

Graphical abstract: Precursor chemistry of metal nitride nanocrystals

Article information

Article type
Review Article
Submitted
04 Aug. 2021
Accepted
08 Okt. 2021
First published
15 Nov. 2021
This article is Open Access
Creative Commons BY-NC license

Nanoscale, 2021,13, 18865-18882

Precursor chemistry of metal nitride nanocrystals

M. Parvizian and J. De Roo, Nanoscale, 2021, 13, 18865 DOI: 10.1039/D1NR05092C

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