Isonicotinic acid-templated metal phosphate–oxalates: solvent-free synthesis, luminescence, and proton conduction

Lijuan Huang; Haiping Xu; Yan Zhao; Ling Huang; Jian Bi; Hongmei Zeng; Guohong Zou; Daojiang Gao; Zhien Lin

doi:10.1039/D1CE00873K

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Isonicotinic acid-templated metal phosphate–oxalates: solvent-free synthesis, luminescence, and proton conduction†

Lijuan Huang,^ab Haiping Xu,^a Yan Zhao,^b Ling Huang,

^b Jian Bi,^b Hongmei Zeng,^a Guohong Zou,

^a Daojiang Gao

*^b and Zhien Lin

*^a

Author affiliations

* Corresponding authors

^a College of Chemistry, Sichuan University, Chengdu 610064, China
E-mail: zhienlin@scu.edu.cn

^b College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610068, China
E-mail: daojianggao@sicnu.edu.cn

Abstract

Two new metal phosphate–oxalates (denoted SCU-26 and SCU-27) were prepared under solvent-free conditions using isonicotinic acid as a structure-directing agent. SCU-26 has a neutral layered structure showing intense blue-green luminescence with a high quantum yield of 28.35%. SCU-27 has an anionic layered structure with a high proton conductivity of 9.0 × 10⁻⁴ S cm⁻¹ at 85 °C under 95% relative humidity.

This article is part of the themed collection: Crystal Engineering Techniques

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DOI: https://doi.org/10.1039/D1CE00873K
Article type: Communication
Submitted: 02 Jūl. 2021
Accepted: 27 Sept. 2021
First published: 27 Sept. 2021

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CrystEngComm, 2021,23, 6855-6858

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Isonicotinic acid-templated metal phosphate–oxalates: solvent-free synthesis, luminescence, and proton conduction

L. Huang, H. Xu, Y. Zhao, L. Huang, J. Bi, H. Zeng, G. Zou, D. Gao and Z. Lin, CrystEngComm, 2021, 23, 6855 DOI: 10.1039/D1CE00873K

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CrystEngComm

Isonicotinic acid-templated metal phosphate–oxalates: solvent-free synthesis, luminescence, and proton conduction†

Abstract

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Isonicotinic acid-templated metal phosphate–oxalates: solvent-free synthesis, luminescence, and proton conduction

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