Issue 39, 2021

Isonicotinic acid-templated metal phosphate–oxalates: solvent-free synthesis, luminescence, and proton conduction

Abstract

Two new metal phosphate–oxalates (denoted SCU-26 and SCU-27) were prepared under solvent-free conditions using isonicotinic acid as a structure-directing agent. SCU-26 has a neutral layered structure showing intense blue-green luminescence with a high quantum yield of 28.35%. SCU-27 has an anionic layered structure with a high proton conductivity of 9.0 × 10−4 S cm−1 at 85 °C under 95% relative humidity.

Graphical abstract: Isonicotinic acid-templated metal phosphate–oxalates: solvent-free synthesis, luminescence, and proton conduction

Supplementary files

Article information

Article type
Communication
Submitted
02 Jūl. 2021
Accepted
27 Sept. 2021
First published
27 Sept. 2021

CrystEngComm, 2021,23, 6855-6858

Isonicotinic acid-templated metal phosphate–oxalates: solvent-free synthesis, luminescence, and proton conduction

L. Huang, H. Xu, Y. Zhao, L. Huang, J. Bi, H. Zeng, G. Zou, D. Gao and Z. Lin, CrystEngComm, 2021, 23, 6855 DOI: 10.1039/D1CE00873K

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