Issue 25, 2021

Solid-state behaviors of imines: colossal biaxial positive thermal expansion, motion capability, and phase transitions

Abstract

Pedal motion or static disorder in single-component solids containing imine groups is demonstrated. Unique solid-state behaviors including colossal biaxial positive thermal expansion in one solid and a temperature-dependent phase transition in another are discussed. Imines exhibit torsional flexibility, which differs from the isoelectronic azo and olefin groups and influences solid-state behaviors.

Graphical abstract: Solid-state behaviors of imines: colossal biaxial positive thermal expansion, motion capability, and phase transitions

Supplementary files

Article information

Article type
Communication
Submitted
28 Maijs 2021
Accepted
06 Jūn. 2021
First published
07 Jūn. 2021

CrystEngComm, 2021,23, 4439-4443

Author version available

Solid-state behaviors of imines: colossal biaxial positive thermal expansion, motion capability, and phase transitions

N. Juneja, E. Zahid, D. K. Unruh and K. M. Hutchins, CrystEngComm, 2021, 23, 4439 DOI: 10.1039/D1CE00706H

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