Issue 34, 2021

Determining the mechanisms of deformation in flexible crystals using micro-focus X-ray diffraction

Abstract

While the first report of molecular crystals that could bend without breaking was well over a decade ago, the development of suitable characterisation tools remains a priority. Due to the broad reaching applications of these materials in advanced technologies, it is important to develop both mechanical and mechanistic understanding. Micro-focused mapping experiments were designed with the intent of bridging the gap between the measurement of mechanical properties and molecular-scale structural understanding. Herein, we describe a methodology for determining the mechanisms of deformation in flexible crystals with atomic precision and provide examples where it has been implemented. Although micro-focused mapping experiments have potential for application in the determination of mechanisms of flexibility, great care must be taken during both experimental design and data analysis.

Graphical abstract: Determining the mechanisms of deformation in flexible crystals using micro-focus X-ray diffraction

Article information

Article type
Highlight
Submitted
25 Marts 2021
Accepted
10 Maijs 2021
First published
10 Maijs 2021

CrystEngComm, 2021,23, 5731-5737

Determining the mechanisms of deformation in flexible crystals using micro-focus X-ray diffraction

A. J. Thompson, A. Worthy, A. Grosjean, J. R. Price, J. C. McMurtrie and J. K. Clegg, CrystEngComm, 2021, 23, 5731 DOI: 10.1039/D1CE00401H

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